Recent advances in polyoxothiometalate chemistry

نویسندگان

چکیده

Despite the proliferation of tungstate and molybdate polyoxometalates (POMs) inclusion sulfides into these structures proved to be challenging. The use appropriate preformed thiomolybdate building blocks has over recent years developed an extensive field with a wide range diverse structural features sizes. Initial explorations focused largely either on combinatorial approach POM dimeric units or self-condensation which gave ring-shaped structures. Over past ten archetypes have been challenged; new design approaches led generation fundamentally multicomponent systems featuring well-defined fragments can self-organize in numerous different ways forming variety features, often remarkably high nuclearity. unique properties tunability potential system proven valuable, examples POTM exhibiting highly motifs promising catalytic applications. In this mini-review we describe methodologies that used construct materials important properties. discussion does not aim provide exhaustive review but rather focuses developments occurred last decade.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Recent advances in spin chemistry*

The great success in controlling chemical reactivity by spin manipulation was achieved in the last decade, and many remarkable spin and magnetic phenomena have been discovered. Among those discoveries, the most chemically important highlights are magnetic isotope effect, spin catalysis, and single-spin tunneling spectroscopy. This paper summarizes recent advances in these new and hot areas of m...

متن کامل

Recent advances in planar tetracoordinate carbon chemistry

We summarize our contributions on the quest of new planar tetracoordinate carbon entities (new carbon molecules with exotic chemical structures and strange bonding schemes). We give special emphasis on the rationalization why in this type of molecules the planar configuration is favored over the tetrahedral one. We will concentrate on the latter and will show that molecules containing planar te...

متن کامل

Recent Advances in Hemophilia Gene Therapy

Heterogeneous loss of function mutations at F8 and F9 genes causes X-linked recessive bleeding disorders, hemophilia A (HA) and hemophilia B (HB), respectively. HA is clinically indistinguishable from HB and accounts for more than 80% of hemophilia cases; the former affects 1/5000 and the latter 1/25000 male births worldwide. In Iran, it is estimated that around 4300 HA and 900 HB patients are ...

متن کامل

Recent Advances in Chemistry in Relation to Medical Practice

In the preface to this edition the author says, "The surgical as well as all other arts are most effective when presented with the greatest simplicity. This book attempts to eliminate the nonessential." The enthusiasm which this statement arouses is somewhat dampened on finding that the early chapters contain several purely facetious remarks, quotations of such favorite phrases of the author as...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Coordination Chemistry

سال: 2022

ISSN: ['1029-0389', '0095-8972', '1026-7441']

DOI: https://doi.org/10.1080/00958972.2022.2086049